Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon

戴国飞; 甘南琴; 宋立荣; 方少文; 彭宁彦

doi:10.1007/s00343-018-7181-y

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Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon

ICTC-10 Special Issue: Cyanobacteria and cyanotoxins: responses and detection | Updated：2023-05-19

- Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon
- Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon
- 海洋湖沼学报（英文） 2018年36卷第4期页码：1103-1111
- Affiliations：
  
  1.Jiangxi Provincial Key Laboratory of Water Resources and Environment of Poyang Lake, Jiangxi Institute of Water Sciences, Nanchang 330029, China
  2.Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072, China
  3.College of Life Science, Nanchang University, Nanchang 330031, China
- Author bio：
  
  DAI Guofei, daiguofei@whu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(31660138);the National Natural Science Foundation of China(31400405);the Jiangxi Water Science and Technology Fund(TG201501);the Jiangxi Water Science and Technology Fund(KT201602);the Science and Technology Project from Ministry of Water Resources, China(ZXKT201508);the Science and Technology Project from Ministry of Water Resources, China(SKY201503)
- DOI：10.1007/s00343-018-7181-y
  中图分类号：
- 收稿：2017-06-15，
  
  录用：2017-8-14，
  
  网络首发：2017-10-31，
  
  纸质出版：2018-07
- Accepted：
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戴国飞, 甘南琴, 宋立荣, 等. Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon[J]. 海洋湖沼学报（英文）, 2018,36(4):1103-1111.

Guofei DAI, Nanqin GAN, Lirong SONG, et al. Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(4): 1103-1111.
戴国飞, 甘南琴, 宋立荣, 等. Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon[J]. 海洋湖沼学报（英文）, 2018,36(4):1103-1111. DOI： 10.1007/s00343-018-7181-y.

Guofei DAI, Nanqin GAN, Lirong SONG, et al. Fast adsorption of microcystin-LR by Fe(Ⅲ)-modified powdered activated carbon[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(4): 1103-1111. DOI： 10.1007/s00343-018-7181-y.

摘要

Abstract

Microcystins (MCs) are cyclic hepatotoxic peptides produced by the bloom-forming cyanobacterium

Microcystis

and present a public health hazard to humans and livestock. The removal of MCs from contaminated water with powdered activated carbon (PAC) has been employed as a simple and economic treatment strategy. In this study

PAC-Fe(Ⅲ) was prepared and utilized for the fast and efficient removal of MCs from water. PAC-Fe(Ⅲ) exhibited superior microcystin-LR (MC-LR) removal capacity and efficiency compared to the unmodified PAC. The MC-LR removal efficiency of PAC-Fe(Ⅲ) increased with decreasing pH within the pH range of 4.3 to 9.6. PAC-Fe(Ⅲ) could be reused for 3 times by methanol elution while the MC-LR removal efficiency was still over 70 percent. The removal efficiency was positively correlated to the ionic strength of water and negatively correlated to alkalinity. Natural organic matter (NOM) such as humic acid (HA) and salicylic acid (SA) generated low interference with MC-LR adsorption by PAC-Fe(Ⅲ). The complexation reaction between Fe

in PAC-Fe(Ⅲ) and the functional groups of MCLR was suggested as the key mechanism of MC-LR removal by PAC-Fe(Ⅲ). The results suggest that Femodified PAC is a promising material for the treatment of MC-contaminated waters.

关键词

Keywords

references

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