Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea

张耀玲; 杨克利; 杜金洲; 张芬芬; 董亚萍; 李武

doi:10.1007/s00343-017-6202-6

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Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea

Chemistry | Updated：2023-05-19

- Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea
- Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea
- 海洋湖沼学报（英文） 2018年36卷第2期页码：238-248
- Affiliations：
  
  1.Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
  2.State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062, China
- Author bio：
  
  DU Jinzhou, jzdu@sklec.ecnu.edu.cn
- Funds：
  
  the National Natural Science Foundation of China(41403108);the West Light Foundation of the Chinese Academy of Sciences(Y412011004);the Natural Science Foundation of Qinghai Province(2014-ZJ-937Q)
- DOI：10.1007/s00343-017-6202-6
  中图分类号：
- 收稿：2016-08-02，
  
  录用：2016-9-22，
  
  网络首发：2016-11-17，
  
  纸质出版：2018-03
- Accepted：
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张耀玲, 杨克利, 杜金洲, 等. Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea[J]. 海洋湖沼学报（英文）, 2018,36(2):238-248.

Yaoling ZHANG, Keli YANG, Jinzhou DU, et al. Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(2): 238-248.
张耀玲, 杨克利, 杜金洲, 等. Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea[J]. 海洋湖沼学报（英文）, 2018,36(2):238-248. DOI： 10.1007/s00343-017-6202-6.

Yaoling ZHANG, Keli YANG, Jinzhou DU, et al. Chemical characterization of fractions of dissolved humic substances from a marginal sea-a case from the Southern Yellow Sea[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(2): 238-248. DOI： 10.1007/s00343-017-6202-6.

摘要

Abstract

Marine dissolved organic matter (DOM) is one of the largest dynamic pools of organic carbon in the global carbon cycle

yet DOM is still chemically poorly characterized. To better understand the origin

composition

and cycling of DOM in the China marginal sea

dissolved humic substances (DHS) were isolated from seawaters in two locations in the Southern Yellow Sea. The DHS were subdivided into fulvic acids (FAs)

humic acids (HAs) and the XAD-4 fractions. Complementary analytical approaches were used to characterize the isolated DHS samples including stable carbon isotopic composition

Fourier transform infrared spectroscopy (FTIR)

C cross polarization magic angle spinning (CP/MAS) nuclear magnetic resonance (NMR)

and pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). The results demonstrated that both DHS samples encountered the influences from marine source

indicating that algal and microbial-derived materials are the predominant precursors for the studied samples. The three fractions of DHS showed different properties. FAs presented more aromatic features

whereas HAs contained more aliphatic lipids and proteinaceous materials. The XAD-4 fractions were enriched in

C and contained more carbohydrates but less aromatic compounds. The lower molecular weight and higher heteroatom content and number of carboxyl groups for the XAD-4 fractions may give them considerable geochemical significance for aspects of trace metal species

bioavailability of pollutants

mineral weathering and water acidification in marine environments.

关键词

Keywords

references

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