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Institute of Oceanology Chinese Academy of Sciences
网络首发:2014-03-06,
纸质出版:2014
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Occurrence and distribution of dissolved tellurium in Changjiang River estuary[J]. 海洋湖沼学报(英文), 2014,32(2):444-454.
Wu, X., Song, J. & Li, X. Occurrence and distribution of dissolved tellurium in Changjiang River estuary., Chin. J. Ocean. Limnol. 32, 444–454 (2014). https://doi.org/10.1007/s00343-014-3161-z
Occurrence and distribution of dissolved tellurium in Changjiang River estuary[J]. 海洋湖沼学报(英文), 2014,32(2):444-454. DOI: 10.1007/s00343-014-3161-z.
Wu, X., Song, J. & Li, X. Occurrence and distribution of dissolved tellurium in Changjiang River estuary., Chin. J. Ocean. Limnol. 32, 444–454 (2014). https://doi.org/10.1007/s00343-014-3161-z DOI:
With the implementation of the GEOTRACES program
the biogeochemical cycle and distribution of tellurium (Te) in marine environments are becoming increasing environmental concerns. In this study
the concentration of dissolved Te in the Changjiang (Yangtze) River estuary and nearby waters was determined in May 2009 by hydride-generation atomic fluorescence spectrometry to elucidate the abundance
dominant species
distribution
and relationship with environmental factors. Results show that: (1) dissolved Te was low owing to its low abundance in the Earth’s crust
high insolubility in water
and strong affinity to particulate matter; (2) Te(IV) and Te(VI) predominated in surface water. Te(VI) was the dominant species in bottom water
and Te(IV) was the minor species; (3) Horizontally
resulting from low phytoplankton metabolism and the weak reduction from Te(VI) to Te(IV) in the shore
Te(IV) was concentrated in the central zone instead of the coastal region. However
Te(VI) was abundant near the mouth of the Changjiang River where the Changjiang water is diluted and in the area to the south where the Taiwan Warm Current invaded. In the adsorption-desorption process
Te(IV) was negatively related to suspended particulate matter (SPM)
indicating that it was adsorbed by particulate matter. While for Te(VI)
the positive correlation with SPM suggested that it was desorbed from the solid phase. In the estuary
dissolved Te had a negative correlation to salinity. However
it deviated from the dilution line in high-salinity regions due to the invasion of the Taiwan Warm Current and the mineralization of organic matter. The relationship between Te(IV) and SPM nutrients indicated that it was more bioavailable and more related to phosphorus than to nitrogen. Progress in the field is slow and more research is needed to quantify the input of Te to the estuary and evaluate the biochemical role of organisms.
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