Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors

Mei Fu; Zhiming Yu; Guangyuan Lu; Xiuxian Song

doi:10.1007/s00343-013-2212-1

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Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors

OriginalPaper | Updated：2023-05-16

- Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors
- Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors
- 海洋湖沼学报（英文） 2013年31卷第4期页码：860-866
- Affiliations：
  
  1. Key Laboratory of Marine Ecology and Environmental Sciences Institute of Oceanology Chinese Academy of Sciences
  2. University of Chinese Academy of Sciences
- Author bio：
- Funds：
  
  Supported by the National Natural Science Foundation of China (Nos. 30970522, 40576058) and the National Natural Science Foundation of China for Creative Research Groups (No. 41121064)
- DOI：10.1007/s00343-013-2212-1
  中图分类号：
- 网络首发：2013-07-10，
  
  纸质出版：2013
- Accepted：
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Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors[J]. 海洋湖沼学报（英文）, 2013,31(4):860-866.

Fu, M., Yu, Z., Lu, G. et al. Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors., Chin. J. Ocean. Limnol. 31, 860–866 (2013). https://doi.org/10.1007/s00343-013-2212-1
Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors[J]. 海洋湖沼学报（英文）, 2013,31(4):860-866. DOI： 10.1007/s00343-013-2212-1.

Fu, M., Yu, Z., Lu, G. et al. Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors., Chin. J. Ocean. Limnol. 31, 860–866 (2013). https://doi.org/10.1007/s00343-013-2212-1 DOI：

摘要

Abstract

The Henry’s Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH

temperature

and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23°C). This value increases with increases in temperature and salinity

but no obvious change was observed at different pH levels. At the same temperature

there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry’s Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater

and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.

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references

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