Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera

Hui Zhao; Huaxiao Yan; Ming Liu; Congwang Zhang; Song Qin

doi:10.1007/s00343-011-0095-6

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Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera

OriginalPaper | Updated：2023-05-16

- Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera
- Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera
- 海洋湖沼学报（英文） 2011年29卷第5期页码：996-1001
- Affiliations：
  
  1. Institute of Oceanology Chinese Academy of Sciences
  2. Graduate University of Chinese Academy of Sciences
  3. Shandong University of Science and Technology
  4. Institute of Process Engineering Chinese Academy of Sciences
- Author bio：
- Funds：
  
  Supported by the National Natural Science Foundation of China (No. 21076117), Shandong Province Higher Educational Science and Technology Program (Nos. J09LC22 and J10LC15), the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCX2-YW-209), and the Open Fund of the Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences (No. Kf201016);ZHAO Hui and YAN Huaxiao contributed equally to this paper
- DOI：10.1007/s00343-011-0095-6
  中图分类号：
- 网络首发：2011-08-08，
  
  纸质出版：2011
- Accepted：
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Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera[J]. 海洋湖沼学报（英文）, 2011,29(5):996-1001.

Zhao, H., Yan, H., Liu, M. et al. Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera, ., Chin. J. Ocean. Limnol. 29, 996–1001 (2011). https://doi.org/10.1007/s00343-011-0095-6
Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera[J]. 海洋湖沼学报（英文）, 2011,29(5):996-1001. DOI： 10.1007/s00343-011-0095-6.

Zhao, H., Yan, H., Liu, M. et al. Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera, ., Chin. J. Ocean. Limnol. 29, 996–1001 (2011). https://doi.org/10.1007/s00343-011-0095-6 DOI：

摘要

Abstract

The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao

China

during the summers of 2007

2008 and 2010. It is thus a plentiful source of biomass and could be used as a biofuel. In this study

the pyrolytic characteristics and kinetics of E. prolifera were investigated using thermogravimetric analysis (TGA) method. Cornstalk and sawdust were used as comparisons. Pyrolytic characteristics were studied using TG-DTG (thermogravimetry-derivative thermogravimetry) curves. Three stages in the pyrolytic process were determined: dehydration

dramatic weight loss and slow weight loss. E. prolifera was pyrolyzed at a lower initial temperature than the two terrestrial biomass forms. The apparent activation energy values for the three types of biomass were calculated and the mechanism functions were determined using 16 different mechanism functions

frequently used in thermal kinetics analysis. Activation energy values varied with mechanism function and the range of activation energy values for E. prolifera

cornstalk

and sawdust were 25–50 kJ/mol

60–90 kJ/mol and 120–155 kJ/mol

respectively. This indicates that E. prolifera has low thermal stability for pyrolysis and good combustion characteristics.

关键词

Keywords

references

Babu B V, Chaurasia A S. 2004. Pyrolysis of biomass: improved models for simultaneous kinetics and transport of heat, mass and momentum. Ener. Conver. Manag., 45(9–10): 1 297–1 327.

Ebrahimi-Kahrizsangi R, Abbasi M H. 2008. Evaluation of reliability of Coats-Redfern method for kinetic analysis of non-isothermal TGA. Transactions of Nonferrous Metals Society of China, 18: 217–221.

French R, Czernik S. 2010. Catalytic pyrolysis of biomass for biofuels production. Fuel Proces. Technol., 91(1): 25–32.

Hu R Z, Shi Q Z. 2001. Thermal Analysis Kinetics. 1st edn. Science Press, Beijing, China. p.1–206. (in Chinese)

Ille J, Hindrek T, Laine T. 2004. A step-by-step model for pyrolysis kinetics of polyethylene in an autoclave under non-linear increase of temperature. J. Anal. Appl. Pyrolysis., 72(1): 113–119.

Jaber J O, Badran O O, Abu-Shikhah N. 2004. Sustainable energy and environmental impact: role of renewables as clean and secure source of energy for the 21st century in Jordan. Clean Technol. Envir. Policy, 6(3): 174–186.

Jeguirim M, Trouvé G. 2009. Pyrolysis characteristics and kinetics of Arundo donax using thermogravimetric analysis. Biores. Technol., 100(17): 4 026–4 031.

Jiang G Z, Nowakowski D J, Bridgwater A V. 2010. A systematic study of the kinetics of lignin pyrolysis. Thermochim. Acta, 498(1–2): 61–66.

Koh L P, Ghazoul J. 2008. Biofuels, biodiversity, and people: Understanding the conflicts and finding opportunities. Bio. Conserv., 141(10): 2 450–2 460.

Li D M, Chen L M, Zhao J S, Zhang X W, Wang Q Y, Wang H X, Ye N H. 2010. Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China. Chem. Eng. Res. Des., 88(5–6): 647–652.

Li L Q, Chen D H. 2004. Application of iso-temperature method of multiple rate to kinetic analysis. J. Therm. Anal. Calorim. 78(1): 283–93.

Li Z J, Shen X Q, Feng X, Wang P Y, Wu Z S. 2005. Non-isothermal kinetics studies on the thermal decomposition of zinc hydroxide carbonate. Thermochim. Acta, 438(1–2): 102–106.

Mata T M, Martins A A, Caetano N S. 2010. Microalgae for biodiesel production and other applications: A review. Renew. Sust. Energy Rev., 14: 217–232.

Ngo T A, Kim J, Kim S S. 2010. Characteristics and kinetics of cattle litter pyrolysis in a tubing reactor. Biores. Technol., 101(1, s1): s104–s108.

Órfão J J M, Figueiredo J L. 2001. A simplified method for determination of lignocellulosic materials pyrolysis kinetics from isothermal thermogravimetric experiments. Thermochim. Acta, 380(1): 67–78.

Pan P, Hu C W, Yang W Y, Li Y S, Dong L L, Zhu L F, Tong D M, Qing R W, Fan Y. 2010. The direct pyrolysis and catalytic pyrolysis of Nannochloropsis sp. residue for renewable bio-oils. Biores. Technol., 101(12): 4 593–4 599.

Rourke F O, Boyle F, Reynolds A. 2009. Renewable energy resources and technologies applicable to Ireland. Renew. Sust. Ener. Rev., 13(8): 1 975–1 984.

Van de Velden M, Baeyens J, Brems A, Janssens B, Dewil R. 2010. Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction. Renew. Ener., 35(1): 232–242.

Vlaev L, Nedelchev N, Gyurova K, Zagorcheva M. 2008. A comparative study of non-isothermal kinetics of decomposition of calcium oxalate monohydrate. J. Anal. Appl. Pyrolysis, 81(2): 253–262.

Wang N, Wang S, Yu L J, Jiang X M. 2008. Analysis on Combustion Characteristics of Algae. Boiler Technology, 39(2): 75–80. (in Chinese with English abstract)

Xiong S M, Zuo X F, Zhu Y Y. 2005. Determination of cellulose, hemi-cellulose and Ligin in rice hull. Cereal Feed Indus., 8: 40–41. (in Chinese with English abstract)

Zhou D, Zhang L, Zhang S C, Fu H B, Chen J M. 2010. Hydrothermal liquefaction of macroalgae Enteromorpha prolifera to bio-oil. Energy Fuels, 24(7): 4 054–4 061.

Zou S P, Wu Y L, Yang M D, Li C, Tong J M. 2010. Pyrolysis characteristics and kinetics of the marine microalgae Dunaliella tertiolecta using thermogravimetric analyzer. Biores. Technol., 101(1): 359–365.

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