Ultrasonic-assisted condensation of chitosan with salicylaldehyde

Lihong Duan; Siyuan Guo; Jinqing Yang; Shengquan Ye; Zhaomei Wang; Kaijun Xiao; Bisheng Zheng

doi:10.1007/s00343-009-9204-1

Your Location：

Home >

Browse articles >

Ultrasonic-assisted condensation of chitosan with salicylaldehyde

OriginalPaper | Updated：2023-05-16

- Ultrasonic-assisted condensation of chitosan with salicylaldehyde
- Ultrasonic-assisted condensation of chitosan with salicylaldehyde
- 海洋湖沼学报（英文） 2009年27卷第4期页码：882-886
- Affiliations：
  
  Light Industry & Chemical Engineering Research Institute South China University of Technology
- Author bio：
- Funds：
  
  Supported by Doctoral Discipline Special Foundation, Education Ministry of China (No. 20050561014), and the National High Technology Research and Development Program of China (863 Program) (No. 2007AA100405)
- DOI：10.1007/s00343-009-9204-1
  中图分类号：
- 网络首发：2009-12-04，
  
  纸质出版：2009
- Accepted：
Scan QR Code
Ultrasonic-assisted condensation of chitosan with salicylaldehyde[J]. 海洋湖沼学报（英文）, 2009,27(4):882-886.

Duan, L., Guo, S., Yang, J. et al. Ultrasonic-assisted condensation of chitosan with salicylaldehyde., Chin. J. Ocean. Limnol. 27, 882–886 (2009). https://doi.org/10.1007/s00343-009-9204-1
Ultrasonic-assisted condensation of chitosan with salicylaldehyde[J]. 海洋湖沼学报（英文）, 2009,27(4):882-886. DOI： 10.1007/s00343-009-9204-1.

Duan, L., Guo, S., Yang, J. et al. Ultrasonic-assisted condensation of chitosan with salicylaldehyde., Chin. J. Ocean. Limnol. 27, 882–886 (2009). https://doi.org/10.1007/s00343-009-9204-1 DOI：

摘要

Abstract

In order to synthesize an improved adsorbent for heavy metal ions

we studied the condensation reaction of chitosan with salicylaldehyde in ethanol to form a Schiff base. The effect irradiating the reaction using an ultrasonic liquid processor was contrasted with conventional methods. The IR spectra of condensed chitosan prepared by the two methods showed that their molecular structures were identical. The reaction conditions

including solvents

ultrasonic power density and irradiation time

and reactant ratio

were optimized by orthogonal design. A shorter reaction time and a higher product yield were obtained using ultrasonic-assisted synthesis compared with the traditional method. A condensation degree of 89.63% was achieved using the optimized conditions: i.e. ultrasonic irradiation at 180 W for 60 min; 95% ethanol as the solvent

pH 4.0

and salicylaldehyde:chitosan ratio of 6:1.

关键词

Keywords

references

Chan P, Kurisawa M, Chung J E, Yang Y Y. 2007. Synthesis and characterization of chitosan-g-poly(ethylene glycol)-folate as a non-viral carrier for tumor-targeted gene delivery. Biomaterials, 28: 540–549.

Crini G, Badot P M. 2008. Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature. Progress in Polymer Science, 33: 399–447.

Drofenik M, Kristl M, Makovec D, Jagličić Z, Hanžel D. 2008. Sonochemically assisted synthesis of zinc-doped maghemite. Ultrasonics Sonochemistry, 15: 791–798.

Ghasemi S, Mousavi M F, Shamsipur M, Karami H. 2008. Sonochemical-assisted synthesis of nano-structured lead dioxide. Ultrasonics Sonochemistry, 15: 448–455.

Jayakumar R, Nwe N, Tokura S, Tamura H. 2007. Sulfated chitin and chitosan as novel biomaterials. International Journal of Biological Macromolecules, 40: 175–181.

Kim I Y, Seo S J, Moon H S. 2008. Chitosan and its derivatives for tissue engineering applications. Biotechnology Advances, 26: 1–21.

Kim T H, Jiang H L, Dhananjay J. 2007. Chemical modification of chitosan as a gene carrier in vitro and in vivo. Progress in Polymer Science, 32: 726–753.

Krajewska B. 2005. Membrane-based processes performed with use of chitin/chitosan materials. Separation and Purification Technology, 41: 305–312.

Ma G. 2008. Preparation and characterization of water-soluble N-alkylated chitosan. Carbohydrate Polymers, 74: 121–126.

Majeti N V, Ravi K. 2000. A review of chitin and chitosan applications. Reactive & Functional Polymers, 46: 1–27.

Manuel G, Antonio S N, Maria E M. 1992. A derivative of chitosan and 2,4-pentanedione with strong chelating properties. Carbohydrate Research, 233: 255–259.

Neppolian B, Wang Q, Jung H, Choi H. 2008. Ultrasonic-assisted sol-gel method of preparation of TiO2 nano-particles: Characterization, properties and 4-chlor-ophenol removal application. Ultrasonics Sonochemistry, 15: 649–658.

Qu R, Ma Q, Zheng X, Sun Y. 1995. Preparation of chitosan derivatives and their adsorption behavior. Chinese Journal of Applied Chemistry, 12: 117–118.

Pasanphan W, Chirachanchai S. 2008. Conjugation of gallic acid onto chitosan: An approach for green and water-based antioxidant. Carbohydrate Polymers, 72: 169–177.

Perrin D D, interpreted by Shi Y. 1987. Purified methods of chemical leechdom in laboratory, Chemical industry publishing company. 320p.

Qu R, Zheng X, Sun Y. 1995. Preparation of chitosan derivatives and their adsorption behavior. Chinese Journal of Applied Chemistry, 12: 117–118.

Rinaudo M. 2006. Chitin and chitosan: Properties and applications. Progress in Polymer Science, 31: 603–632.

Schuetz Y B, Gurny R, Jordan O. 2008. A novel thermoresponsive hydrogel based on chitosan. European Journal of Pharmaceutics and Biopharmaceutics, 68: 19–25.

Sinha V R, Singla A K, Wadhawan S, Kaushik R, Kumria R, Bansal K, Dhawan S. 2004. Chitosan microspheres as a potential carrier for drugs. International Journal of Pharmaceutics, 274: 1–33.

Stavarache C, Vinatoru M, Maeda Y. 2007. Aspects of ultrasonically assisted transesterification of various vegetable oils with methanol. Ultrasonics Sonochemistry, 14: 380–386.

Tian X L, Liu Z. 1997. Study of condensation chitosan by salicylaldehyde. Chinese Journal of Guangxi Normal University, Supplement: 268–272. (in Chinese)

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Synthesis and properties of sulfhydryl chitosan

Preparation, characterization, and antifungal activity of hymexazol-linked chitosan derivatives

基于最大似然估计的点火概率曲线计算模型取点方法

一种涡轮基组合动力的整机低速风洞试验研究

2.5D编织结构复合材料温度场特征研究