Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics

Wang Xiulin; Zhang Zhengbin; Liu Liansheng

doi:10.1007/BF02850675

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Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics

OriginalPaper | Updated：2023-05-16

- Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics
- Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics
- 海洋湖沼学报（英文） 1991年9卷第2期页码：163-169
- Affiliations：
  
  Ocean University of Qingdao
- Author bio：
- Funds：
- DOI：10.1007/BF02850675
  中图分类号：
- 纸质出版：1991
- Accepted：
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Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics[J]. 海洋湖沼学报（英文）, 1991,9(2):163-169.

Xiulin, W., Zhengbin, Z. & Liansheng, L. Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics., Chin. J. Ocean. Limnol. 9, 163–169 (1991). https://doi.org/10.1007/BF02850675
Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics[J]. 海洋湖沼学报（英文）, 1991,9(2):163-169. DOI： 10.1007/BF02850675.

Xiulin, W., Zhengbin, Z. & Liansheng, L. Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics., Chin. J. Ocean. Limnol. 9, 163–169 (1991). https://doi.org/10.1007/BF02850675 DOI：

摘要

Abstract

IR spectra of Cu (II)-marine solid particle systems show that Cu(II)-marine solid particle ion exchange causes a stepwise change in the surface H-bonding hydroxyl groups on illite

montmorillonite

CaCO3

γ-AlOOH and goethite

but that this does not affect the surface free hydroxyl groups on illite

montmorillonite and CaCO3

and framework hydroxyl group on goethite and on γ-AlOOH. Over the range of Cu (II) exchange amounts in the present experiment

four stepwise changes were discovered for the surface H-bonding hydroxyl group on illite

while two stepwise changes were observed on the other marine solids. The interfacial stepwise ion exchange theory was first demonstrated by the above experimental evidence.

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references

Cambier R., 1986. Infrared study of goethite of varying crystalinity and particle size: I. Interpretation of OH and lattice vibration frequences.Clay Minerals 21: 191–200.

Ishikawa T., S. Nitta and S. Kondo, 1986. Fourier-transform infrared spectroscopy of colloidal α-, β-and γ-ferric hydroxide.J. Chem. Soc., Faraday Trans. I. 82: 2401–2410.

Lewis D. G. and V. C. Former, 1986. Infrared absorption of surface hydroxyl groups and lattice vibration in lepidocrocite and boehmite.Clay Minerals 25: 93–100.

Zhang Zhengbin, 1990. Estuarine-Marine Chemistry of Huanghe Estuary. Springer-Verlag, Berlin.

Zhang Zhengbin and Liu Liansheng, 1985. Theory of Interfacial Stepwise Ion/Coordination Particle Exchange and Its Application. China Ocean Press, Beijing, pp. 357.

Zhang Zhengbin and Liu Liansheng, 1987. The isotherm of stepwise ion exchange between Cu(II). Zn(II), Cd(II) and γ-Al2O3 in seawater.Oceanol. Limnol. Sinica 18(1): 76–85 (in Chinese).

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