The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry

Gu Hong-kan

doi:10.1007/BF02850588

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The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry

OriginalPaper | Updated：2023-05-16

- The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry
- The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry
- 海洋湖沼学报（英文） 1997年15卷第1期页码：88-91
- Affiliations：
  
  Institute of Oceanology
- Author bio：
- Funds：
  
  Contribution No. 3068 from the Institute of Occanology, Chinese Academy of Sciences.;The project supported by the NSFC.
- DOI：10.1007/BF02850588
  中图分类号：
- 纸质出版：1997
- Accepted：
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The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry[J]. 海洋湖沼学报（英文）, 1997,15(1):88-91.

Hong-kan, G. The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry., Chin. J. Ocean. Limnol. 15, 88–91 (1997). https://doi.org/10.1007/BF02850588
The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry[J]. 海洋湖沼学报（英文）, 1997,15(1):88-91. DOI： 10.1007/BF02850588.

Hong-kan, G. The functional relation between ion concentration in water vapor chemistry and the bond parameter in quantum chemistry., Chin. J. Ocean. Limnol. 15, 88–91 (1997). https://doi.org/10.1007/BF02850588 DOI：

摘要

Abstract

The functional relation between “water vapor chemistry” ion concentration and the “quantum chemistry” bond parameter is (I z/Z)VN=1/(a+b/C)a=0.627

b=0.234

R=0.988

S=0.0721 whereI z/Z is specific electron affinity constant (as hydration force)

I z is last ionization potential

Z is ion valence

V is ion volume

N is coordination number (as hydration number)

C is ion concentration (μg/L) in condensed water of water vapor;R is correlation coefficient

S is standard deviation;a andb are constants. The corresponding correlation curve shows thatC has positive correlation toI z/Z and negative correlation toVN.

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Keywords

references

Chen, N., 1976. Bond Parameter Function and its Application, Science Press, Beijing, 109 pp. (in Chinese).

Green, J., 1959. Geochemical table of the elements for 1959.Bulletin of the Geological Society of America (1962), 70(9): 80. Chinese translation.

Gu Hongkan, 1988. Analysis, speciation, distribution, and toxicity of trace metals in natural waters. International Corference on Trace Metals in Lakes, Hamilton, Canada, Abstract 32. See also: Proceedings of the Second General Assembly of the Division of Earth Sciences, the Chinese Academy of Scineces, Science Press, Beijing, 249–252(in Chinese).

Gu Hongkan. 1988. Water-water vapor transfer of trace metal ions in nature and model.Marine Sciences 3(4) 71–76 (1991).

Gu Hongkan (Editor in Chief). 1991. Marine Chemistry of the Bohai Sea, the Yellow Sea and the East China Sea, Science Press, Beijing, 500 pp (in Chinese).

Gu Hongkan, Liu Mingxing Bao Wanyou, 1982. Anti-adsorption physically coated mercury film electrode for inverse polarography.Chin J. Oceanol. Limnol.1(1): 76–81.

Gu Hongkan, Liu Mingxing, Li Guoji et al. 1984. The anomaly of thermodynamics in trace physico-chemical system.Chin. J. Oceanol. Limnol. 2(2): 125–132.

Gu Hongkan, Liu Mingxing, Li Guoji et al. 1986. Original natural water formed from Zn2+-saturated water vapor.Acta Oceanologica Sinica 5(2): 229–234.

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