Inhibitor-concentration-induced extreme behaviour in electrochemical parameters

Wang Jia

doi:10.1007/BF02845186

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Inhibitor-concentration-induced extreme behaviour in electrochemical parameters

OriginalPaper | Updated：2023-05-16

- Inhibitor-concentration-induced extreme behaviour in electrochemical parameters
- Inhibitor-concentration-induced extreme behaviour in electrochemical parameters
- 海洋湖沼学报（英文） 1998年16卷第2期页码：183-188
- Affiliations：
  
  Institute of Oceanology
- Author bio：
- Funds：
  
  Contribution No. 3048 from the Institute of Oceanology, Chinese Academy of Sciences
- DOI：10.1007/BF02845186
  中图分类号：
- 纸质出版：1998
- Accepted：
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Inhibitor-concentration-induced extreme behaviour in electrochemical parameters[J]. 海洋湖沼学报（英文）, 1998,16(2):183-188.

Jia, W. Inhibitor-concentration-induced extreme behaviour in electrochemical parameters., Chin. J. Ocean. Limnol. 16, 183–188 (1998). https://doi.org/10.1007/BF02845186
Inhibitor-concentration-induced extreme behaviour in electrochemical parameters[J]. 海洋湖沼学报（英文）, 1998,16(2):183-188. DOI： 10.1007/BF02845186.

Jia, W. Inhibitor-concentration-induced extreme behaviour in electrochemical parameters., Chin. J. Ocean. Limnol. 16, 183–188 (1998). https://doi.org/10.1007/BF02845186 DOI：

摘要

Abstract

Changes in electrochemical parameters and inhibition performance with inhibitor concentration were investigated by electrochemical measurements of propargyl derivative inhibitors in acidic solution. It was found that with increasing inhibitor concentrations

double layer capacitances

polarization resistances and inhibiting efficiencies showed extreme behavior at certain inhibitor concentration in sulfuric acid but not in hydrochloric acid medium. Analysis of the changes in desorption and corrosion potentials with inhibitor concentration showed that this extreme phenomenon resulted from inhibitor desorption occurring at around corrosion potential in sulfuric acid solution as the inhibitor concentration reached this certain value.

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references

Epelboin, I., Gabrielli C., Kedadam, M. et al., 1979. Altermating-current impedance measurements applied to corrosion studies and corrosion rate determination, Proc.ASTM Symp. Progress in Electrochemical Corrosion Testing, Eds. Mansfeld F. and Bertocci U., NACE, p.150.

Chandrasekara Pillai K., Narayan, R., 1983. Organic inhibitors of corrosion.Corr. Sci. 23 (3): 151.

Wang Jia, Cao Chunan, Liang Feng, 1991. On the Inhibition Action of Some Inhibitors. Proc. 7th Asian Pacific Corrosion Control Corference, Chinese Society of Corrosion and Protection, Beijing, p.991–993.

Wang Jia, 1997. Inhibitor effects on the anodic behaviour of iron electrode.Chin J. Oceanol. Limnol. 15(2): 156–162.

Wang Jia, Shi Chunyn, Song Shizhe et al., 1989. Curve fitting for the impedance data with dispersing capacitive loops.J. Chin. Soc. Corr. Prot,9: 11–16.

Wang Jia, Chen Jiajian, Cao Dianzhen et al., 1991. An investigation of the electrochemical behaviour of N.N-Dipropynoxy methyl alkyl amine inhibitors.J. Chin. Soc. Corr. Prot,11: 38–41.

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