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The intrinsic acidity constants and specific surface area of marine solid particles[J]. 海洋湖沼学报(英文), 1992,10(1):68-74.
Xiulin, W., Zhengbin, Z. & Liansheng, L. The intrinsic acidity constants and specific surface area of marine solid particles., Chin. J. Ocean. Limnol. 10, 68–74 (1992). https://doi.org/10.1007/BF02844301
The intrinsic acidity constants and specific surface area of marine solid particles[J]. 海洋湖沼学报(英文), 1992,10(1):68-74. DOI: 10.1007/BF02844301.
Xiulin, W., Zhengbin, Z. & Liansheng, L. The intrinsic acidity constants and specific surface area of marine solid particles., Chin. J. Ocean. Limnol. 10, 68–74 (1992). https://doi.org/10.1007/BF02844301 DOI:
This paper deals with the infrared spectra of “amino acid-clay
calcium carbonate and γ-AlOOH” and “Cu(II)-clay-amino acid” model systems
and shows that the model of the ternary surface complex is M-OHLCu (L=amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area
and especially the intrinsic acidity constant
determine whether the ternary surface complex is easily formed
and that factor
F TSC
quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.
Davis, J.A. and J.O. Leckie, 1978. Effect of adsorbed complexing ligand and trace metal uptake by hydrous oxide.Environ. Sci. Technol. 12: 1309–1315.
Elliott, H.A. and C.P. Huang, 1980. Adsorption of some copper (II)-amino acid complexes at the solid-solution interface. Effect of liquid and surface hydrophobicity.Environ. Sci. Technol. 14(1): 87–93.
Huang, C.P., 1981. In “Adsorption of Inorganics at Solid-Liquid Interfaces”, eds. M.A. Anderson and A.J. Rubin. Ann. Arbor Science, Michigan, pp. 357.
Krauskopf, K.B., 1956. Factor controlling the concentration of thirteen trace metals in seawater.Geochim. Cosmochim. Acta 12: 61–81.
Lewis, D.G. and V.C. Former, 1986. Infrared absorption of surface hydroxyl group and lattice vibration in lepidocrocite and boehmite.Clay Minerals 25: 93–100.
Marx, U., R. Sokoll and H. Hobert, 1986. Thermal desorption and infrared studies of primary aliphatic amines adsorbed on haematite.J. Chem. Soc., Faraday Trans. I. 82: 2505–2514.
Misra, B.N. and R. Kripal, 1984. Infrared study of some amino acids and their copper complexes.Indian J. Pure & Applied Physics 22: 430–432.
Wang Xiulin, Zhang Zhengbin and Liu Liansheng, 1987. The effect of amino acid on copper (II)-goethite ion exchange in seawater.Chin. J. Oceanol. Limnol 5(2): 134–146.
Wang Xiulin, Zhang Zhengbin and Liu Liansheng, 1988. The surface reaction on liquid-solid interface of amino acid-Cu(II)−MnO2 systems in seawater.Chin: J. Oceanol. Limnol. 6(3): 258–271.
Wang Xiulin, Zhang Zhengbin and Liu Liansheng, 1989. The effect of amino acid on Cu(II)−CaCO3 ion exchange in seawater. Symposium on Marine Chemistry. Ocean Press, Beijing, pp. 43–51. (in Chinese)
Wang Xiulin, 1989. The interaction among trace metal ions, organics and solid particle in seawater. Ph. D Thesis, Ocean University of Qingdao, Qingdao. (in Chinese)
Wang Xiulin, Zhang Zhengbin and Liu Liansheng, 1991. The intrinsic acidity constants and specific surface area of marine solid particles I. A new method.Chin: J. Oceanol. Limnol. 9(3): 253–262.
Zhang Zhengbin and Liu Liansheng, 1985. Theory of Interfacial Stepwise Ion/Coordination Particles Exchange and Its Applications. Ocean Press, Beijing, pp. 357.
Zhang Zhengbin 1991. Estuarine-Marine Chemistry of Huanghe Estuary, Springer-Verlag, Berlin.
Zhang Zhengbin, Liu Liansheng, Wang Xiulin et al, 1987. The surface ion exchange of amino acid-Cd(II), Zn(II)−MnO2 systems in seawater.Oceanol. Limnol. Sinica 18(5): 450–458, (in Chinese with English abstract)
Zhang Zhengbin and Liu Liansheng, 1989. Marine Physicochemistry, Science Press, Beijing, pp. 808. (in Chinese)
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