Seasonal and spatial variations in rare earth elements and yttrium of dissolved load in the middle, lower reaches and estuary of the Minjiang River, southeastern China

Xuxu ZHU; Aiguo GAO; Jianjie LIN; Xing JIAN; Yufeng YANG; Yanpo ZHANG; Yuting HOU; Songbai GONG

doi:10.1007/s00343-018-6207-9

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Seasonal and spatial variations in rare earth elements and yttrium of dissolved load in the middle, lower reaches and estuary of the Minjiang River, southeastern China

Chemistry | Updated：2023-05-19

- Seasonal and spatial variations in rare earth elements and yttrium of dissolved load in the middle, lower reaches and estuary of the Minjiang River, southeastern China
- Chinese Journal of Oceanology and Limnology Vol. 36, Issue 3, Pages: 700-716(2018)
- Affiliations：
  
  1.College of Ocean and Earth Sciences, Xiamen University, Xiamen 361102, China
  2.State Key Laboratory of Marine Environmental Sciences, Xiamen 361102, China
  3.Marine and Fisheries Technology Center of Fuzhou, Fuzhou 350026, China
- Author bio：
  
  GAO Aiguo, aggao@xmu.edu.cn
- Funds：
- DOI：10.1007/s00343-018-6207-9
  CLC：
- Received：05 September 2016，
  
  Accepted：10 November 2016，
  
  Online First：13 April 2017，
  
  Published：2018-05
- Accepted：
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Xuxu ZHU, Aiguo GAO, Jianjie LIN, et al. Seasonal and spatial variations in rare earth elements and yttrium of dissolved load in the middle, lower reaches and estuary of the Minjiang River, southeastern China[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(3): 700-716.
DOI：

Xuxu ZHU, Aiguo GAO, Jianjie LIN, et al. Seasonal and spatial variations in rare earth elements and yttrium of dissolved load in the middle, lower reaches and estuary of the Minjiang River, southeastern China[J]. Chinese Journal of Oceanology and Limnology, 2018, 36(3): 700-716. DOI： 10.1007/s00343-018-6207-9.

摘要

Abstract

With the aim of elucidating the spatial and seasonal behaviors of rare earth elements (REEs)

we investigated the dissolved REE concentrations of surface water collected during four seasons from middle

lower reaches and estuary of the Minjiang River

southeastern China. The results display that the REE abundances in Minjiang River

ranging from 3.3-785.9 ng/L

were higher than those of many of the major global rivers. The total REE concentrations (∑REE) were seasonally variable

averaging in 5 937.30

863.79

825.65 and 1 065.75 ng/Lduring second highest flow (SHF)

normal flow (NF)

low flow (LF) and high flow (HF) season

respectively. The

(L/M)

and

(H/M)

ratios reveal the spatial and temporal variations of REE patterns

and particularly vary apparently in the maximum turbidity zone and estuary. REE patterns of dissolved loads are characterized by progressing weaker LREEs-enrichment and stronger HREEsenrichment downstream from middle reaches to estuary during all four seasons. Comparing with NF and LF seasons

in which REE patterns are relatively flat

samples of SHF season have more LREE-enriched and HREE-depleted patterns that close to parent rocks

while samples of HF season are more LREEs-depleted and HREE-enriched. REE fractionations from the middle to lower reaches are stronger in the SHF and HF seasons than those in NF and LF seasons. Generally

spatial and seasonal variations in REE abundance and pattern are presumably due to several factors

such as chemical weathering

mixture with rainfall and groundwater

estuarine mixing

runoff

biological production and mountain river characters

such as strong hydrodynamic forces and steep slopes. The highest Gd/Gd

always occurs at north ports during all four seasons

where most of the large hospitals are located. This suggests Gd anomalies are depended on the density of modern medical facilities. Y/Ho ratios fluctuate and positively correlate to salinity in estuary

probably because of the geochemical behavior differences between Y and Ho.

关键词

Keywords

references

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