A simple method to model the reduced environment of lake bottom sapropel formation

Olga L. Gaskova; Vera D. Strakhovenko; Nadezhda I. Ermolaeva; Eugene Yu. Zarubina; Ekaterina A. Ovdina

doi:10.1007/s00343-017-5345-9

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A simple method to model the reduced environment of lake bottom sapropel formation

Updated：2023-05-16

- A simple method to model the reduced environment of lake bottom sapropel formation
- Journal of Oceanology and Limnology Vol. 35, Issue 4, Pages: 956-966(2017)
- Affiliations：
  
  1. . S. Sobolev Institute of Geology and Mineralogy Siberian Branch of the Russian Academy of Sciences,V
  2. Novosibirsk State University
  3. Institute for Water and Environmental Problems Siberian Branch of the Russian Academy of Sciences
- Author bio：
- Funds：
- DOI：10.1007/s00343-017-5345-9
  CLC：
- Online First：28 July 2016，
  
  Published：2017
- Accepted：
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Gaskova, O.L., Strakhovenko, V.D., Ermolaeva, N.I. et al. A simple method to model the reduced environment of lake bottom sapropel formation., Chin. J. Ocean. Limnol. 35, 956–966 (2017). https://doi.org/10.1007/s00343-017-5345-9
DOI：

Gaskova, O.L., Strakhovenko, V.D., Ermolaeva, N.I. et al. A simple method to model the reduced environment of lake bottom sapropel formation., Chin. J. Ocean. Limnol. 35, 956–966 (2017). https://doi.org/10.1007/s00343-017-5345-9 DOI：

摘要

Abstract

The Kambala and Barchin brackish lakes (Baraba steppe

southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters. We measured the bulk sediment elemental composition

the water chemistry and determined the mineralogical composition and predominant biota species (Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes. The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one. A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes. The surface sodium bicarbonate waters are supersaturated with respect to calcite

magnesite (or low Mg-calcite)

quartz and chlorite with minor strontianite

apatite and goethite (pH 8.9–9.3

Eh 0.3 V). Nevertheless

it is shown that during sapropel deposition

deep silt waters should be anoxic (Eh<0 V). The virtual component CH2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction. Thermodynamic calculation has shown that silt water is not necessarily euxinic (anoxic and sulfidic). Depending on Eh

sulfate sulfur can dominate in solution

causing the formation of gypsum together with pyrite. An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.

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references

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