Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating

Xia Zhao; Shuan Liu; Xiutong Wang; Baorong Hou

doi:10.1007/s00343-014-3327-8

Your Location：

Home >

Browse articles >

Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating

Updated：2023-05-16

- Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating
- Journal of Oceanology and Limnology Vol. 32, Issue 5, Pages: 1163-1171(2014)
- Affiliations：
  
  1. Key Laboratory of Marine Environmental Corrosion and Bio-fouling Institute of Oceanology Chinese Academy of Sciences
  2. Ningbo Institute of Material Technology & Engineering Chinese Academy of Sciences
- Author bio：
- Funds：
- DOI：10.1007/s00343-014-3327-8
  CLC：
- Online First：11 July 2014，
  
  Published：2014
- Accepted：
Scan QR Code
Zhao, X., Liu, S., Wang, X. et al. Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating., Chin. J. Ocean. Limnol. 32, 1163–1171 (2014). https://doi.org/10.1007/s00343-014-3327-8
DOI：

Zhao, X., Liu, S., Wang, X. et al. Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating., Chin. J. Ocean. Limnol. 32, 1163–1171 (2014). https://doi.org/10.1007/s00343-014-3327-8 DOI：

摘要

Abstract

The surface of ZrO2 nanoparticles was modified by styrene coupling grafting method to improve the dispersion and interaction of the nanoparticles with the epoxy coating in which the modified ZrO2 nanoparticles were used as an additive. The grafting performance and microstructure of the nano-ZrO2/epoxy coating were analyzed by Fourier transformation infrared spectroscopy

X-ray diffraction

and scanning electron microscopy. The corrosion behavior of the nano-ZrO2/epoxy coating on mild steel was evaluated in neutral 3.5 wt% NaCl solution using electrochemical impedance spectroscopy (EIS). Both the coating capacitance and coating resistance fitted by the equivalent circuit from EIS were used to evaluate the protective performance of the coating towards the mild steel. The results show a superior stability and efficient corrosion protection by the modified ZrO2 nanoparticles. The epoxy coating containing 2 wt% modified ZrO2 nanoparticles exhibited the best corrosion performance among all the coating specimens. This research may provide an insight into the protection of mild steel using modified epoxy coatings.

关键词

Keywords

references

Andreatta F, Aldighieri P, Paussa L, Maggio R D, Rossi S, Fedrizzi L. 2007. Electrochemical behaviour of ZrO2 solgel pre-treatments on AA6060 aluminium alloy. Electrochimica Acta, 52: 7 545–7 555.

Balamurugan A, Kannan S, Rajeswari S. 2003. Structural and electrochemical behaviour of sol-gel zirconia films on 316L stainless-steel in simulated body fluid environment. Materials Letters, 57: 4 202–4 205.

Behzadnasab M, Mirabedini S M, Kabiri K, Jamali S. 2011. Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution. Corrosion Science, 53: 89–98.

Cheng Y L, Zhang Z, Cao F H, Li J F, Zhang J Q, Wang J, Cao C N. 2004. A study of the corrosion of aluminum alloy 2024-T3 under thin electrolyte layers. Corrosion Science, 46: 1 649–1 667.

Gao L, Song X Q. 2008. Controlled preparation and spectral analysis of nanorod and nanocluster ZrO2. Materials Chemistry and Physics, 110: 52–55.

Gonzalez E, Paveza J, Azocar I, Zagal J H, Zhou X, Melo F, Thompson G E, Páeza M A. 2011. A silanol-based nanocomposite coating for protection of AA-2024 aluminium alloy. Electrochimica Acta, 56: 7 586–7 595.

Jacek G, Che C, Bogdan S. 2013. Effect of a ZrO2 coating deposited by the sol-gel method on the resistance of FeCrAl alloy in high-temperature oxidation conditions. Materials Chemistry and Physics, 139: 944–952.

Jiang Z Q, Jiang Z J, Shi Y C, Meng Y D. 2010. Preparation and characteristics of acrylic acid/styrene composite plasma polymerized membranes. Applied Surface Science, 256: 6 473–6 479.

Liang J, Srinivasan P B, Blawert C, Dietzel W. 2009. Comparison of electrochemical corrosion behaviour of MgO and ZrO2 coatings on AM50 magnesium alloy formed by plasma electrolytic oxidation. Corrosion Science, 51: 2 483–2 492.

Liu S, Sun H Y, Sun L J, Fan H J. 2012. Effects of pH and Cl− concentration on corrosion behavior of the galvanized steel in simulated rust layer solution. Corrosion Science, 65: 520–527.

Liu S, Zhang Y, Gu Y, Huang Y P. 2013a. Degradation of organic pollutants by a Co3O4-graphite composite electrode in an electro-Fenton-like system. Chinese Science Bulletin, 58: 2 340–2 346.

Liu S, Zhao X R, Sun H Y, Huang Y P. 2013b. The degradation of tetracycline in a photoelectro-Fenton system. Chemical Engineering Journal, 231: 441–448.

Liu Z, Yan D R, Dong Y C, Yang Y, Chu Z H, Zhang Z. 2013. The effect of modified epoxy sealing on the electrochemical corrosion behaviour of reactive plasma-sprayed TiN coatings. Corrosion Science, 75: 220–227.

Nishikata A, Ichihara Y, Hayashi Y, Tsuru T. 1997. Infl uence of electrolyte layer thickness and ph on the initial stage of the atmospheric corrosion of iron. J ournal of Electrochem ical Soc iety, 144(4): 1 244–1 252.

Olad A, Barati M, Behboudi S. 2012. Preparation of PANI/epoxy/Zn nanocomposite using Zn nanoparticles and epoxy resin as additives and investigation of its corrosion protection behavior on iron. Progress in Organic Coatings, 74: 221–227.

Sandhyarani M, Rameshbabu N, Venkateswarlu K, Sreekanth D, Subrahmanyam C. 2013. Surface morphology, corrosion resistance and in vitro bioactivity of P containing ZrO2 films formed on Zr by plasma electrolytic oxidation. J ournal of Alloys and Compounds, 553: 324–332.

Vishwanath G, Deshmane Y G. 2012. Synthesis of thermally stable, high surface area, nanocrystalline mesoporous tetragonal zirconium dioxide (ZrO2): effects of different process parameters. Microporous and Mesoporous Materials, 148: 88–100.

Wang M J, Li C F, Yen S K. 2013. Electrolytic MgO/ZrO2 duplex-layer coating on AZ91D magnesium alloy for corrosion resistance. Corrosion Science, 76: 142–153.

Xue D C, Van Ooij W J. 2013. Corrosion performance improvement of hot-dipped galvanized (HDG) steels by electro-deposition of epoxy-resin-ester modified bis-[triethoxysilyl] ethane (BTSE) coatings. Progress in Organic Coatings, 76: 1 095–1 102.

Zou Y, Wang J, Zheng Y Y. 2011. Electrochemical techniques for determining corrosion rate of rusted steel in seawater. Corrosion Science, 53: 208–216.

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Effect of co-alloying of In and Nd on the marine corrosion behavior of AZ63 magnesium alloys

Electrochemical corrosion behavior of hot dip coating in artificial seawater

Effect of sulphate-reducing bacteria on electro-chemical corrosion behavior of 16Mn steel in sea mud

Corrosion performance of zinc coated steel in seawater environment

Multivariable Constrained Model Predictive Control ofAero-Engine Based on Augmented Predictive Model

Related Author

Ying LI

Lei WANG

Jiarun LI

Zhenyu ZHANG

Zhibo ZHAO

Zhenxu XU

Yang ZHOU

Chongqing GUO

Related Institution

Qingdao University of Science and Technology

Shandong Sunhe New Material Technology Co., Ltd.

Institute of Oceanology Chinese Academy of Sciences

Nonferrous Metallurgical Department Northeastern University

Shenyang Agriculture University

Address：Editorial Office of JOL, 88 Haijun Rd. Qingdao, 266000, China
Tel：+86-532-82898754 Email：jol@qdio.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备09064830号-19 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰