Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors

Mei Fu; Zhiming Yu; Guangyuan Lu; Xiuxian Song

doi:10.1007/s00343-013-2212-1

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Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors

Updated：2023-05-16

- Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors
- Journal of Oceanology and Limnology Vol. 31, Issue 4, Pages: 860-866(2013)
- Affiliations：
  
  1. Key Laboratory of Marine Ecology and Environmental Sciences Institute of Oceanology Chinese Academy of Sciences
  2. University of Chinese Academy of Sciences
- Author bio：
- Funds：
- DOI：10.1007/s00343-013-2212-1
  CLC：
- Online First：10 July 2013，
  
  Published：2013
- Accepted：
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Fu, M., Yu, Z., Lu, G. et al. Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors., Chin. J. Ocean. Limnol. 31, 860–866 (2013). https://doi.org/10.1007/s00343-013-2212-1
DOI：

Fu, M., Yu, Z., Lu, G. et al. Henry’s law constant for phosphine in seawater: determination and assessment of influencing factors., Chin. J. Ocean. Limnol. 31, 860–866 (2013). https://doi.org/10.1007/s00343-013-2212-1 DOI：

摘要

Abstract

The Henry’s Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH

temperature

and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23°C). This value increases with increases in temperature and salinity

but no obvious change was observed at different pH levels. At the same temperature

there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry’s Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater

and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus.

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