

FOLLOWUS
1. Key Laboratory of Marine Geology and Environment Institute of Oceanology Chinese Academy of Sciences
2. Graduate University of Chinese Academy of Sciences
3. National Marine Environmental Monitoring Center
Online First:25 October 2011,
Published:2011
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Lu, B., Li, T., Yu, X. et al. Redox conditions in sediments and during sedimentation in the Ontong Java Plateau, west equatorial Pacific., Chin. J. Ocean. Limnol. 29, 1309–1324 (2011). https://doi.org/10.1007/s00343-011-1027-1
Redox-sensitive elements in sediments
such as manganese (Mn)
vanadium (V)
molybdenum (Mo)
and uranium (U)
are promising indicators of past redox conditions during sedimentation and early diagenesis. However
in the Ontong Java Plateau
west equatorial Pacific
there are sparse datasets of redox-sensitive elements in sediment cores. Here
we present a 250 ka record of redox sensitive elements from a 460 cm gravity core at site WP7 (3°56′S
156°E
water depth 1 800 m)
which was recovered from the southwest Ontong Java Plateau during the 1993 cruise of R/V Science I of the Institute of Oceanology
Chinese Academy of Sciences (IOCAS). Relative to the Post-Archean Australian Shale (PAAS)
authigenic Mn
cobalt (Co)
nickel (Ni)
Mo
V
U
and cadmium (Cd) were found at constantly low levels except when peaks occurred at several depth intervals. Manganese
Co
Ni
and Mo concentrations were elevated at 25–35 cm due to Mn redox cycling. The core was divided into three distinct sections
the top 0–25 cm being oxic
a suboxic section at 25–35 cm and from 35–460 cm which was anoxic. Differential authigenic enrichments of Co
Ni
Mo
V
U
and Cd at the same depth intervals were observed indicating that the enrichments happened during sedimentation or diagenesis and suffered no post settlement redox changes. Therefore
no significant changes in redox conditions during sedimentation must have happened. The water at depth on the Ontong Java Plateau during past 250 ka must have been well oxygenated
possibly resulted from the more or less continuous presence of oxygen-rich deep water like the modern Antarctic Intermediate Water (AAIW) and Antarctic Circumpolar Water (ACW); while it’s slightly less oxygenated in glacial intervals
possibly due to ventilation weakening and/or the surface productivity increase.
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