Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera

Hui Zhao; Huaxiao Yan; Ming Liu; Congwang Zhang; Song Qin

doi:10.1007/s00343-011-0095-6

Your Location：

Home >

Browse articles >

Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera

Updated：2023-05-16

- Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera
- Journal of Oceanology and Limnology Vol. 29, Issue 5, Pages: 996-1001(2011)
- Affiliations：
  
  1. Institute of Oceanology Chinese Academy of Sciences
  2. Graduate University of Chinese Academy of Sciences
  3. Shandong University of Science and Technology
  4. Institute of Process Engineering Chinese Academy of Sciences
- Author bio：
- Funds：
- DOI：10.1007/s00343-011-0095-6
  CLC：
- Online First：08 August 2011，
  
  Published：2011
- Accepted：
Scan QR Code
Zhao, H., Yan, H., Liu, M. et al. Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera, ., Chin. J. Ocean. Limnol. 29, 996–1001 (2011). https://doi.org/10.1007/s00343-011-0095-6
DOI：

Zhao, H., Yan, H., Liu, M. et al. Pyrolytic characteristics and kinetics of the marine green tide macroalgae, Enteromorpha prolifera, ., Chin. J. Ocean. Limnol. 29, 996–1001 (2011). https://doi.org/10.1007/s00343-011-0095-6 DOI：

摘要

Abstract

The marine macroalgae Enteromorpha prolifera was one of the main algal genera that occurred in the widespread green tides in Qingdao

China

during the summers of 2007

2008 and 2010. It is thus a plentiful source of biomass and could be used as a biofuel. In this study

the pyrolytic characteristics and kinetics of E. prolifera were investigated using thermogravimetric analysis (TGA) method. Cornstalk and sawdust were used as comparisons. Pyrolytic characteristics were studied using TG-DTG (thermogravimetry-derivative thermogravimetry) curves. Three stages in the pyrolytic process were determined: dehydration

dramatic weight loss and slow weight loss. E. prolifera was pyrolyzed at a lower initial temperature than the two terrestrial biomass forms. The apparent activation energy values for the three types of biomass were calculated and the mechanism functions were determined using 16 different mechanism functions

frequently used in thermal kinetics analysis. Activation energy values varied with mechanism function and the range of activation energy values for E. prolifera

cornstalk

and sawdust were 25–50 kJ/mol

60–90 kJ/mol and 120–155 kJ/mol

respectively. This indicates that E. prolifera has low thermal stability for pyrolysis and good combustion characteristics.

关键词

Keywords

references

Babu B V, Chaurasia A S. 2004. Pyrolysis of biomass: improved models for simultaneous kinetics and transport of heat, mass and momentum. Ener. Conver. Manag., 45(9–10): 1 297–1 327.

Ebrahimi-Kahrizsangi R, Abbasi M H. 2008. Evaluation of reliability of Coats-Redfern method for kinetic analysis of non-isothermal TGA. Transactions of Nonferrous Metals Society of China, 18: 217–221.

French R, Czernik S. 2010. Catalytic pyrolysis of biomass for biofuels production. Fuel Proces. Technol., 91(1): 25–32.

Hu R Z, Shi Q Z. 2001. Thermal Analysis Kinetics. 1st edn. Science Press, Beijing, China. p.1–206. (in Chinese)

Ille J, Hindrek T, Laine T. 2004. A step-by-step model for pyrolysis kinetics of polyethylene in an autoclave under non-linear increase of temperature. J. Anal. Appl. Pyrolysis., 72(1): 113–119.

Jaber J O, Badran O O, Abu-Shikhah N. 2004. Sustainable energy and environmental impact: role of renewables as clean and secure source of energy for the 21st century in Jordan. Clean Technol. Envir. Policy, 6(3): 174–186.

Jeguirim M, Trouvé G. 2009. Pyrolysis characteristics and kinetics of Arundo donax using thermogravimetric analysis. Biores. Technol., 100(17): 4 026–4 031.

Jiang G Z, Nowakowski D J, Bridgwater A V. 2010. A systematic study of the kinetics of lignin pyrolysis. Thermochim. Acta, 498(1–2): 61–66.

Koh L P, Ghazoul J. 2008. Biofuels, biodiversity, and people: Understanding the conflicts and finding opportunities. Bio. Conserv., 141(10): 2 450–2 460.

Li D M, Chen L M, Zhao J S, Zhang X W, Wang Q Y, Wang H X, Ye N H. 2010. Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China. Chem. Eng. Res. Des., 88(5–6): 647–652.

Li L Q, Chen D H. 2004. Application of iso-temperature method of multiple rate to kinetic analysis. J. Therm. Anal. Calorim. 78(1): 283–93.

Li Z J, Shen X Q, Feng X, Wang P Y, Wu Z S. 2005. Non-isothermal kinetics studies on the thermal decomposition of zinc hydroxide carbonate. Thermochim. Acta, 438(1–2): 102–106.

Mata T M, Martins A A, Caetano N S. 2010. Microalgae for biodiesel production and other applications: A review. Renew. Sust. Energy Rev., 14: 217–232.

Ngo T A, Kim J, Kim S S. 2010. Characteristics and kinetics of cattle litter pyrolysis in a tubing reactor. Biores. Technol., 101(1, s1): s104–s108.

Órfão J J M, Figueiredo J L. 2001. A simplified method for determination of lignocellulosic materials pyrolysis kinetics from isothermal thermogravimetric experiments. Thermochim. Acta, 380(1): 67–78.

Pan P, Hu C W, Yang W Y, Li Y S, Dong L L, Zhu L F, Tong D M, Qing R W, Fan Y. 2010. The direct pyrolysis and catalytic pyrolysis of Nannochloropsis sp. residue for renewable bio-oils. Biores. Technol., 101(12): 4 593–4 599.

Rourke F O, Boyle F, Reynolds A. 2009. Renewable energy resources and technologies applicable to Ireland. Renew. Sust. Ener. Rev., 13(8): 1 975–1 984.

Van de Velden M, Baeyens J, Brems A, Janssens B, Dewil R. 2010. Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction. Renew. Ener., 35(1): 232–242.

Vlaev L, Nedelchev N, Gyurova K, Zagorcheva M. 2008. A comparative study of non-isothermal kinetics of decomposition of calcium oxalate monohydrate. J. Anal. Appl. Pyrolysis, 81(2): 253–262.

Wang N, Wang S, Yu L J, Jiang X M. 2008. Analysis on Combustion Characteristics of Algae. Boiler Technology, 39(2): 75–80. (in Chinese with English abstract)

Xiong S M, Zuo X F, Zhu Y Y. 2005. Determination of cellulose, hemi-cellulose and Ligin in rice hull. Cereal Feed Indus., 8: 40–41. (in Chinese with English abstract)

Zhou D, Zhang L, Zhang S C, Fu H B, Chen J M. 2010. Hydrothermal liquefaction of macroalgae Enteromorpha prolifera to bio-oil. Energy Fuels, 24(7): 4 054–4 061.

Zou S P, Wu Y L, Yang M D, Li C, Tong J M. 2010. Pyrolysis characteristics and kinetics of the marine microalgae Dunaliella tertiolecta using thermogravimetric analyzer. Biores. Technol., 101(1): 359–365.

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Estimation and verification of green tide biomass based on UAV remote sensing

Genome-wide SNP markers provided insights into the reproductive strategy and genetic diversity of the green tide causative species Ulva prolifera in China

Interaction between macroalgae and microplastics: Caulerpa lentillifera and Gracilaria tenuistipitata as microplastic bio-elimination vectors

Tempo-spatial distribution of Ulva spp. micro-propagules in the Yellow Sea during and after green tide in 2019

Variations in nano- and pico-eukaryotic phytoplankton assemblages in the Qinhuangdao green-tide area

Related Author

Xiaopeng JIANG

Zhiqiang GAO

Zhicheng WANG

Nan WANG

Song FENG

Yan SUN

Song SUN

Weiwei MA

Related Institution

University of Chinese Academy of Sciences

Shandong Key Laboratory of Coastal Environmental Processes, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences

CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences

Jiaozhou Bay Marine Ecosystem Research Station, Chinese Academy of Sciences

Laboratory for Marine Ecology and Environmental Science, Laoshan Laboratory

Address：Editorial Office of JOL, 88 Haijun Rd. Qingdao, 266000, China
Tel：+86-532-82898754 Email：jol@qdio.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备09064830号-19 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰