Yao, Z. Comparison between BCR sequential extraction and geo-accumulation method to evaluate metal mobility in sediments of Dongting Lake, Central China., Chin. J. Ocean. Limnol. 26, 14–22 (2008). https://doi.org/10.1007/s00343-008-0014-7
DOI:
Yao, Z. Comparison between BCR sequential extraction and geo-accumulation method to evaluate metal mobility in sediments of Dongting Lake, Central China., Chin. J. Ocean. Limnol. 26, 14–22 (2008). https://doi.org/10.1007/s00343-008-0014-7DOI:
Comparison between BCR sequential extraction and geo-accumulation method to evaluate metal mobility in sediments of Dongting Lake, Central China
摘要
Abstract
The form in which a metal exists strongly influences its mobility and thus
the effects on the environment. Operational methods of speciation analysis
such as the use of sequential extraction procedures
are commonly applied. The Dongting Lake
the second largest fresh-water lake in China
contains three China wetlands of international importance
the East Dongting Lake
South Dongting Lake
and West Dongting Lake. In this work
an optimized BCR sequential extraction procedure was used to assess the environmental risk of Cd
Cr
Cu
Ni
Pb and Zn in contaminated sediment of the Dongting Lake. The procedure was evaluated by using a certified reference material
BCR701. The results of the partitioning study indicated that in the lake sediments
more easily mobilized forms (acid exchangeable) were predominant for Cd
particularly in the samples from the East Dongting Lake. In contrast
the largest amount of Pb was associated with the iron and manganese oxide fractions and Cu
Zn
Cr
and Ni analyzed were mainly distributed in residual phase at an average percentage greater than 60% of the total metals. The potential risk to the lake’s water contamination was highest in the East Dongting Lake based on the calculated contamination factors. On the other hand
the total metal content was determined as well by inductively coupled plasma and mass spectrometry (ICP-MS) and assessed by using geo-accumulation index. The assessment results using geo-accumulation index were compared with the information on metal speciation. Both were correspondent with each other.
关键词
Keywords
references
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