Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics

Wang Xiulin; Zhang Zhengbin; Liu Liansheng

doi:10.1007/BF02850675

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Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics

Updated：2023-05-16

- Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics
- Journal of Oceanology and Limnology Vol. 9, Issue 2, Pages: 163-169(1991)
- Affiliations：
  
  Ocean University of Qingdao
- Author bio：
- Funds：
- DOI：10.1007/BF02850675
  CLC：
- Published：1991
- Accepted：
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Xiulin, W., Zhengbin, Z. & Liansheng, L. Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics., Chin. J. Ocean. Limnol. 9, 163–169 (1991). https://doi.org/10.1007/BF02850675
DOI：

Xiulin, W., Zhengbin, Z. & Liansheng, L. Fourier-transform infrared spectroscopic studies on the interaction among marine trace metal ions, solid particles and organics., Chin. J. Ocean. Limnol. 9, 163–169 (1991). https://doi.org/10.1007/BF02850675 DOI：

摘要

Abstract

IR spectra of Cu (II)-marine solid particle systems show that Cu(II)-marine solid particle ion exchange causes a stepwise change in the surface H-bonding hydroxyl groups on illite

montmorillonite

CaCO3

γ-AlOOH and goethite

but that this does not affect the surface free hydroxyl groups on illite

montmorillonite and CaCO3

and framework hydroxyl group on goethite and on γ-AlOOH. Over the range of Cu (II) exchange amounts in the present experiment

four stepwise changes were discovered for the surface H-bonding hydroxyl group on illite

while two stepwise changes were observed on the other marine solids. The interfacial stepwise ion exchange theory was first demonstrated by the above experimental evidence.

关键词

Keywords

references

Cambier R., 1986. Infrared study of goethite of varying crystalinity and particle size: I. Interpretation of OH and lattice vibration frequences.Clay Minerals 21: 191–200.

Ishikawa T., S. Nitta and S. Kondo, 1986. Fourier-transform infrared spectroscopy of colloidal α-, β-and γ-ferric hydroxide.J. Chem. Soc., Faraday Trans. I. 82: 2401–2410.

Lewis D. G. and V. C. Former, 1986. Infrared absorption of surface hydroxyl groups and lattice vibration in lepidocrocite and boehmite.Clay Minerals 25: 93–100.

Zhang Zhengbin, 1990. Estuarine-Marine Chemistry of Huanghe Estuary. Springer-Verlag, Berlin.

Zhang Zhengbin and Liu Liansheng, 1985. Theory of Interfacial Stepwise Ion/Coordination Particle Exchange and Its Application. China Ocean Press, Beijing, pp. 357.

Zhang Zhengbin and Liu Liansheng, 1987. The isotherm of stepwise ion exchange between Cu(II). Zn(II), Cd(II) and γ-Al2O3 in seawater.Oceanol. Limnol. Sinica 18(1): 76–85 (in Chinese).

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Related Author

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Related Institution

Department of Marine Chemistry Shandong College of Oceanology

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