Controlling mechanisms for the trace metals, (Cu, Zn, Cd, Fe, Co and Ni) in anoxic sea water in Saanich Inlet, British Columbia, Canada

Zhan Binqiu; C. S. Wong; W. K. Johnson

doi:10.1007/BF02843983

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Controlling mechanisms for the trace metals, (Cu, Zn, Cd, Fe, Co and Ni) in anoxic sea water in Saanich Inlet, British Columbia, Canada

Updated：2023-05-16

- Controlling mechanisms for the trace metals, (Cu, Zn, Cd, Fe, Co and Ni) in anoxic sea water in Saanich Inlet, British Columbia, Canada
- Journal of Oceanology and Limnology Vol. 5, Issue 3, Pages: 193-204(1987)
- Affiliations：
  
  Institute of Oceanology
- Author bio：
- Funds：
- DOI：10.1007/BF02843983
  CLC：
- Published：1987
- Accepted：
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Binqiu, Z., Wong, C.S. & Johnson, W.K. Controlling mechanisms for the trace metals, (Cu, Zn, Cd, Fe, Co and Ni) in anoxic sea water in Saanich Inlet, British Columbia, Canada., Chin. J. Ocean. Limnol. 5, 193–204 (1987). https://doi.org/10.1007/BF02843983
DOI：

Binqiu, Z., Wong, C.S. & Johnson, W.K. Controlling mechanisms for the trace metals, (Cu, Zn, Cd, Fe, Co and Ni) in anoxic sea water in Saanich Inlet, British Columbia, Canada., Chin. J. Ocean. Limnol. 5, 193–204 (1987). https://doi.org/10.1007/BF02843983 DOI：

摘要

Abstract

A study was conducted on Cu

Co and Ni levels in Saanich Inlet anoxic seawater. Data on the concentration of these trace metals and H2S

and other oceanographic parameters were obtained in four cruises. Equilibrium models are presented together with in situ data. The results strongly support the assumption that the solubilities of Cu

Co and Ni are controlled by bisulfide and/or polysulfide complexes. The species of Cu

Cd and Ni are shown to be Cu(S4) 2 3− and Cu(Sn4S5)3−

Zn(HS) 2 0 and ZnHS 2 −

Cd(HS) 2 0 and Ni(HS) 2 0

respectively. The solid species controlling Fe2+ and Co2+ are respectively the pyrohotites FeS and CoS. The data illustrates that thermodynamic equilibrium has been established in the H2S-controlled seawater of Saanich Inlet

and that equilibrium has not been established in the H2S−O2-coexisted seawater of Saanich Inlet. The lack of equilibrium in the H2S−O2-coexisted seawater is a result of the flushing or mixing of oxygenated seawater with anoxic water. The new species of trace metals are still in the processes of reduction and precipitation.

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references

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