

FOLLOWUS
1.Key Laboratory of Green and High-end Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
2.Qinghai Provincial Key Laboratory of Geology and Environment of Salt Lakes, Xining 810008, China
3.University of Chinese Academy of Sciences, Beijing 100049, China
4.Sichuan Mineral Resources Exploration Group Co., Ltd., Chengdu 610051, China
86014787@qq.com
liqingkuan@isl.ac.cn
收稿:2025-05-31,
修回:2025-08-19,
网络首发:2026-05-07,
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Wenjie LI, Xing LI, Qingkuan LI, 等. Hydrochemistry and formation of shallow-buried brines in the Bankog Co Salt Lake, Xizang[J/OL]. 海洋湖沼学报(英文), 2026,1-15.
LI Wenjie,LI Xing,LI Qingkuan,et al.Hydrochemistry and formation of shallow-buried brines in the Bankog Co Salt Lake, Xizang[J].Journal of Oceanology and Limnology,
Wenjie LI, Xing LI, Qingkuan LI, 等. Hydrochemistry and formation of shallow-buried brines in the Bankog Co Salt Lake, Xizang[J/OL]. 海洋湖沼学报(英文), 2026,1-15. DOI: 10.1007/s00343-025-5187-9.
LI Wenjie,LI Xing,LI Qingkuan,et al.Hydrochemistry and formation of shallow-buried brines in the Bankog Co Salt Lake, Xizang[J].Journal of Oceanology and Limnology, DOI:.
The shallow-buried brines in Bankog Co Salt Lake (BCSL) are characterized by high total dissolved solids (TDS) and K
Li
B
Br concentrations
which is apparently different from the lake waters’
indicating great potential of exploitation. The hydrochemistry and formation of these shallow-buried brines are still mysterious. We collected 17 shallow-buried brine samples
and 4 lake brine samples from various locations in BCSL
and conducted elemental and D-O (deuterium
also known as heavy hydrogen and oxyge
n) isotopic analysis to clarify the solute sources and formation mechanisms of the shallow-buried brines. Results reveal that: (1) the shallow-buried brines are highly mineralized Na-Cl type brines
rich in Na
+
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K
+
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and
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but poor in Ca
2+
and Mg
2+
. Concentrations of trace elements such as Li
+
B
3+
and
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are significantly higher than those in lake brines
and most exceed industrial mining thresholds; (2) the shallow-buried brines showed uneven spatial distribution
with high-concentration zones concentrated in the lake basin center and marginal areas significantly influenced by river dilution
providing spatial guidance for resource exploration and development; (3) D-O isotopes indicate that the brines originated from evaporated meteoric waters and possible mixing with surrounding recharge waters. Some shallow-buried brines exhibit relatively negative δ
18
O and positive δD values
reflecting the influence of regional massive carbonate sedimentation; (4) the shallow-buried brines formation experienced a complex
multi-stage hydrochemical process. The initial meteoric waters underwent evaporation and concentration
forming high-TDS brines dominated by Na
+
and
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. Carbonate precipitation reduced Ca
2+
and Mg
2+
concentrations
while geothermal input contributed Li
+
B
3+
and
<math id="M6"><mi mathvariant="normal">B</mi><msup><mrow><mi mathvariant="normal">r</mi></mrow><mrow><mo>-</mo></mrow></msup></math>
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4.23333359
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. Halite and glauberite dissolution-precipitation regulated Na
+
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and
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proportions. Shallow-buried brines were genetically derived from lake brines and subsequently modified by post-burial processes including groundwater mixing and mineral reactions
developing distinctive geochemical signatures while preserving their genetic connections. This study demonstrated the distinct differences between shallow-buried brines and lake brines in salt lake systems
emphasized the roles of salt mineral dissolution and precipitation
water mixing
and burial in transforming chemical compositions of the shallow-buried brines
thereby advanced the understanding of their formation and evolution.
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