Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific

Hongli ZHU; Long DU; Zhaofeng ZHANG; Weidong SUN

doi:10.1007/s00343-020-0045-2

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Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific

Geology | Updated：2023-04-27

- Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific
- Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific
- 海洋湖沼学报（英文） 2020年38卷第5期页码：1476-1487
- Affiliations：
  
  1.Center of Deep Sea Research, Institute of Oceanography, Chinese Academy of Sciences, Qingdao 266071, China
  2.Laboratory for Marine Mineral Resources, Pilot National Laboratory for Marine Science and Technology(Qingdao), Qingdao 266237, China
  3.Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, China
  4.College of Earth Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
  5.State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
  6.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  DU Long, dulong88@aliyun.com
- Funds：
  
  the National Natural Science Foundation of China(41773009);the National Natural Science Foundation of China(41873002);the Stake Key Laboratory of Geological Processes and Mineral Resources(GPMR201708);the National Science Foundation for Post-doctoral Scientists of China(2018M640660);the Taishan Scholar Program of Shandong(ts201712075);the AoShan Talents Cultivation Program Supported by Qingdao National Laboratory for Marine Science and Technology(2017ASTCP-OS07);© Chinese Society for Oceanology and Limnology, Science Press, and Springer-Verlag Berlin Heidelberg 2020
- DOI：10.1007/s00343-020-0045-2
  中图分类号：
- 收稿：2020-01-19，
  
  录用：2020-3-9，
  
  网络首发：2020-03-15，
  
  纸质出版：2020-09
- Accepted：
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Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific[J]. 海洋湖沼学报（英文）, 2020,38(5):1476-1487.

Hongli ZHU, Long DU, Zhaofeng ZHANG, et al. Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific[J]. Journal of Oceanology and Limnology, 2020, 38(5): 1476-1487.
Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific[J]. 海洋湖沼学报（英文）, 2020,38(5):1476-1487. DOI： 10.1007/s00343-020-0045-2.

Hongli ZHU, Long DU, Zhaofeng ZHANG, et al. Calcium isotopic signatures of depleted mid-ocean ridge basalts from the northeastern Pacific[J]. Journal of Oceanology and Limnology, 2020, 38(5): 1476-1487. DOI： 10.1007/s00343-020-0045-2.

摘要

Abstract

A number of high-temperature processes (e.g.

melt-rock reactions

metasomatism

partial melting) can produce significant Ca isotopic fractionation and heterogeneity in the mantle

but the mechanism for such fractionation remains obscure. To investigate the effect of mantle partial melting on Ca isotopic fractionation

we reported high-precision Ca isotopic compositions of depleted mid-ocean ridge basalts (MORBs) from the East Pacific Rise and Ecuador Rift in the northeastern Pacific. The δ

44/40

Ca of these MORB samples exhibit a narrow variation from 0.84‰ to 0.88‰ with an average of 0.85‰0.03‰

which are similar to those of reported MORBs (0.83‰0.11‰) and back-arc basin basalts (BABBs

0.80‰0.08‰) in literature

but are lower than the estimate value for the bulk silicate Earth (BSE

0.94‰0.05‰). The low δ

44/40

Ca signatures of MORB samples in this study cannot be caused by fractional crystallization

since intermediate-mafic differentiation has been demonstrated having only limited effects on Ca isotopic fractionation. Instead

the offset of δ

44/40

Ca between MORBs and the BSE is most likely produced by mantle partial melting. During this process

the light Ca isotopes are preferentially transferred to the melt

while the heavy ones tend to stay in the residue

which is consistent with the fact that δ

44/40

Ca of melt-depleted peridotites increases with partial melting in literature. The behavior of Ca isotopes during mantle partial melting is closely related to the inter-mineral (Cpx and Opx) Ca isotopic fractionation and melting mineral modes. Mantle partial melting is one of the common processes that can induce lower δ

44/40

Ca values in basalts and Ca isotopic heterogeneity in Earth's mantle.

关键词

Keywords

references

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