Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery

LU Yonghong; YANG Lulu; ZHANG Yue; ZHAO Qing; SANG Lin; DING Fei; XU Haibo

doi:10.1007/s00343-019-9102-0

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Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery

Chemistry | Updated：2023-04-27

- Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery
- Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery
- 海洋湖沼学报（英文） 2020年38卷第2期页码：334-341
- Affiliations：
  
  1.College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China
  2.National Key Laboratory of Science and Technology on Power Sources, Tianjin Institute of Power Sources, Tianjin 300084, China
- Author bio：
  
  XU Haibo, xuwangri@163.com
- Funds：
  
  the National Major Scientific Instruments Development Project of the National Natural Science Foundation of China(41427803);the Zhuang Fa Yu Yan Program(41421020401);© Chinese Society for Oceanology and Limnology, Science Press, and Springer-Verlag Berlin Heidelberg 2020
- DOI：10.1007/s00343-019-9102-0
  中图分类号：
- 收稿：2019-04-15，
  
  录用：2019-5-20，
  
  网络首发：2019-05-24，
  
  纸质出版：2020-02
- Accepted：
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Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery[J]. 海洋湖沼学报（英文）, 2020,38(2):334-341.

LU Yonghong, YANG Lulu, ZHANG Yue, et al. Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery[J]. Journal of Oceanology and Limnology, 2020, 38(2): 334-341.
Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery[J]. 海洋湖沼学报（英文）, 2020,38(2):334-341. DOI： 10.1007/s00343-019-9102-0.

LU Yonghong, YANG Lulu, ZHANG Yue, et al. Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery[J]. Journal of Oceanology and Limnology, 2020, 38(2): 334-341. DOI： 10.1007/s00343-019-9102-0.

摘要

A metal-dissolved oxygen seawater battery (SWB) uses metal and dissolved oxygen as the reactants

and it is ideal for use as a long-time low-power distributed power supply in deep sea

due to its advantages of open structure in service without electrolyte. However

several simulating deep-sea environmental factors

such as flow rate

dissolved oxygen concentration

and temperature of seawater may affect the oxygen reduction reaction (ORR) rate and the stability of electrochemically modified polyacrylonitrile-based carbon fiber brush (MPAN-CFB) cathode

which was studied by steady-state polarization and galvanostatic discharge methods. In addition

the scales formed on MPAN-CFB surface were characterized by SEM and XRD. Results show that the ORR rate increased quickly with the increase of the seawater flow rate up to 3 cm/s

and then gradually stabilized. Moreover

the ORR rate was largely affected by dissolved oxygen concentration

and the concentration of

3 mg/L was favorable. Compared with surface layer temperature of 15℃

the low temperature of deep sea (4℃) has a negligible effect on ORR rate. When the working current is too high

it will lead to the formation of CaCO

scales (aragonite) of at the cathodic surface

resulting in the decrease of ORR rate

and consequently the damage to the long-time stability of MPAN-CFB.

Abstract

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references

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