The apparent copper complexing capacity of seawater and the interaction of copper with humic matter

Sun Mingyi

doi:10.1007/BF02906797

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The apparent copper complexing capacity of seawater and the interaction of copper with humic matter

OriginalPaper | Updated：2023-05-16

- The apparent copper complexing capacity of seawater and the interaction of copper with humic matter
- The apparent copper complexing capacity of seawater and the interaction of copper with humic matter
- 海洋湖沼学报（英文） 1985年3卷第2期页码：224-234
- Affiliations：
  
  Institute of Oceanology
- Author bio：
- Funds：
- DOI：10.1007/BF02906797
  中图分类号：
- 纸质出版：1985
- Accepted：
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The apparent copper complexing capacity of seawater and the interaction of copper with humic matter[J]. 海洋湖沼学报（英文）, 1985,3(2):224-234.

Mingyi, S. The apparent copper complexing capacity of seawater and the interaction of copper with humic matter., Chin. J. Ocean. Limnol. 3, 224–234 (1985). https://doi.org/10.1007/BF02906797
The apparent copper complexing capacity of seawater and the interaction of copper with humic matter[J]. 海洋湖沼学报（英文）, 1985,3(2):224-234. DOI： 10.1007/BF02906797.

Mingyi, S. The apparent copper complexing capacity of seawater and the interaction of copper with humic matter., Chin. J. Ocean. Limnol. 3, 224–234 (1985). https://doi.org/10.1007/BF02906797 DOI：

摘要

Abstract

The anodic stripping voltammetry with physically-coating mercury film electrode was used to investigate the complexing action of trace heavy metals in seawater with organic ligands. The apparent copper complexing capacity of seawater was determined by titrating the organic ligands in natural seawater with standard ionic copper solution. The complexing actions of copper in seawater with humic acid (HA) or fulvic acid (FA) were investigated by titrating copper in seawater with HA or FA solution. The equilibrium time

electrodeposition potential

and effect of pH etc. were investigated respectively. The results show that the interaction of copper in seawater with organic matter is a fast process. At natural pH

HA or FA tend to act with copper in seawater to form nonlabile complexes. During experimental electrode process

these complexes did not significantly dissociate. The experimental results were calculated according to 1∶1 complex formation.

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references

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