The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system

Gu Hongkan; Liu Mingxing; Li Guoji; Bao Wanyou; Zhang Shoulin

doi:10.1007/BF02851484

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The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system

OriginalPaper | Updated：2023-05-16

- The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system
- The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system
- 海洋湖沼学报（英文） 1984年2卷第2期页码：125-132
- Affiliations：
  
  Institute of Oceanology
- Author bio：
- Funds：
  
  Contribution No. 1070 from the Institute of Oceanology, Academia Sinica.
- DOI：10.1007/BF02851484
  中图分类号：
- 纸质出版：1984
- Accepted：
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The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system[J]. 海洋湖沼学报（英文）, 1984,2(2):125-132.

Hongkan, G., Mingxing, L., Guoji, L. et al. The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system., Chin. J. Ocean. Limnol. 2, 125–132 (1984). https://doi.org/10.1007/BF02851484
The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system[J]. 海洋湖沼学报（英文）, 1984,2(2):125-132. DOI： 10.1007/BF02851484.

Hongkan, G., Mingxing, L., Guoji, L. et al. The occurrence of anomaly thermodynamics phenomenon in trace physico-chemical system., Chin. J. Ocean. Limnol. 2, 125–132 (1984). https://doi.org/10.1007/BF02851484 DOI：

摘要

Abstract

The experimental results show that

when the water is evaporated

the trace metal ions Zn2+ etc contained in this water can transfer in 100% concentration to water vapor under the limiting concentration of transfer. Therefore

the free energy

ΔG 0

can not be used directly to predict the feasibility of this trace concentration physico-chemical process. Occurrence of the thermodynamics anomaly phenomenon in trace concentration physico-chemical system is presented experimentally in the present paper.

关键词

Keywords

references

Gu Hongkan, Liu Mingxing, Bao Wanyou et al., 1978. The concentrations of some ions of trace metals in China coastal waters.Studia Marina Sinica 13: 1–7. In Chinese with English abstracts.

Gu Hongkan, Liu Mingxing, Zhang Xingjun et al., 1978. On the concentrations of ions of trace metals in sea water.ibid. 14: 23–27. In Chinese with English abstracts.

Gu Hongkan and Liu Mingxing, 1973. Physically coated mercury film electrode single cell differential inverse polarography.Fenxi Huaxue (Anal. Chem.)1 (1): 15–22. (in Chinese)

Gu Hongkan and Liu Mingxing, 1974. The application of physically coated mercury electrode single cell differential inverse polarography in sea water analysis. I. Zn, Pb and Cu.ibid. 2 (3): 175–179. II. Cd.ibid. Fenxi Huaxue (Anal. Chem.)2 (3): 179–182. (in Chinese)

Gu Hongkan, Liu Mingxing and Bao Wanyou, 1980. A study of the anti-adsorption membrane of electrode.Acta Chim. Sin. 38 (4): 381–386. In Chinese with English abstracts.

Gu Hongkan and Liu Mingxing, 1976. The thermodynamic state of sea water.Studia Marina Sinica 11: 25–31. In Chinese with English abstracts.

Gu Hongkan and Liu Mingxing, 1981. A method for determination of Sn and Bi in sea water using physically coated mercury film electrode inverse polarography.Ocean. Limn. Sin. 12 (5): 427–432. In Chinese with English abstracts.

Gu Hongkan, Liu Mingxing and Li Guoji et al., 1983. On the homogeneous distribution of trace metal ions in natural waters.Kexue Tongbao 17: 1047–1049. (in Chinese)

Gu Hongkan, Liu Mingxing and Bao Wanyou, 1982. Anti-adsorption physically coated mercury film electrode for inverse polarography.Chin. J. Ocean. Limn. 1 (1): 76–81.

Savchenko, A., Smirnov, V. and Svirkunov, P., 1979. Evaporation of impurity ions from solutions into the air.Water, Air and Soil Pollution 12: 407–415.

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