Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid

Luxiao ZHOU; Kun GAO; Peng HE; Huahua YU; Ronge XING; Song LIU; Yukun QIN

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Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid

Biology | Updated：2025-02-19

- Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid
- Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid
- 海洋湖沼学报(英文) 2025年43卷第1期页码：261-273
- Affiliations：
  
  1.College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
  2.CAS and Shandong Province Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
  3.Laboratory for Marine Drugs and Bioproducts, Qingdao Marine Science and Technology Center, Qingdao 266237, China
- Author bio：
  
  hepeng@qust.edu.cn
  ykqin@qdio.ac.cn
- Funds：
  
  the National Natural Science Foundation of China(42076126);the Shandong Key R&D Plan, Major Scientific and Technological Innovation Project(2022CXGC020413);the Natural Science Foundation of Shandong Province(ZR2020MD072;ZR2021QD014);the Liaoning Provincial Natural Science Foundation: Joint Open Fund of the State Key Laboratory for the Creation and Development of New Pesticides(2022-KF-25-03)
- DOI：
  中图分类号：
- 收稿：2024-03-21，
  
  纸质出版：2025-01-01
- Accepted：
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Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid[J]. 海洋湖沼学报(英文), 2025,43(1):261-273.

ZHOU Luxiao,GAO Kun,HE Peng,et al.Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid[J].Journal of Oceanology and Limnology,2025,43(01):261-273.
Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid[J]. 海洋湖沼学报(英文), 2025,43(1):261-273. DOI：

ZHOU Luxiao,GAO Kun,HE Peng,et al.Efficient conversion of chitin to HMF under the co-catalytic system of formic acid and silicotungstic acid[J].Journal of Oceanology and Limnology,2025,43(01):261-273. DOI：

摘要

Abstract

The conversion process of chitin

one of the abundant biomass resources on the earth

not only follows the principles of green chemistry

but also has significant value in industrial applications. However

it is a great challenge to directly convert insoluble and rigid structured chitin to 5-hydroxymethylfurfural (HMF). To address this issue

we developed a green conversion process combining pretreatment and catalytic system. Chitin was first pretreated by hexafluoro isopropanol (HFIP)

which somewhat disrupted the hydrogen bonding network within the chitin structure. Subsequently

formic acid (FA) and silicotungstic acid (STA) synergistically catalyzed the conversion to HMF in a biphasic system of 2-methyltetrahydrofuran (2-Me-THF)/H

and high yields (40.2%) HMF was obtained under the optimism conditions. The product distribution was analyzed by HPLC-MS and the co-catalysis of FA with STA was evidenced. A dual-function catalytic system with both Lewis and Brønsted acids was created

the catalytic system that significantly improved the efficiency of complex tandem catalytic reactions with chitin. Based on the

experimental results

a possible pathway for chitin conversion was deduced

providing a new catalytic idea for the efficient conversion of chitin to HMF.

关键词

Keywords

references

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