Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea

Jingya CAO; Shengxiong YANG; Danling TANG; Junxi FENG; Jinqiang LIANG

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Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea

Geomorphology and geological structure of South China Sea | Updated：2024-10-12

- Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea
- Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea
- 海洋湖沼学报(英文) 2023年41卷第2期页码：660-672
- Affiliations：
  
  1. Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou 511458, China
  2. Department of Ocean Science, Hong Kong University of Science & Technology, Hong Kong 999077, China
  3. MLR Key Laboratory of Marine Mineral Resources, Guangzhou Marine Geological Survey, China Geological Survey, Ministry of Natural Resources, Guangzhou 511458, China
- Author bio：
  
  yangsx@gmlab.ac.cn
- Funds：
  
  the Key Research and Development Project of Guangdong Province(2020B1111510001);the National Natural Science Foundation of China(U2244224);the PI Project of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)(GML2020GD0802);the Guangdong Special Support Key Team Program(2019BT02H594)
- DOI：
  中图分类号：
- 收稿：2022-01-11，
  
  纸质出版：2023-03-01
- Accepted：
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Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea[J]. 海洋湖沼学报(英文), 2023,41(2):660-672.

CAO Jingya,YANG Shengxiong,TANG Danling,et al.Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea[J].Journal of Oceanology and Limnology,2023,41(02):660-672.
Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea[J]. 海洋湖沼学报(英文), 2023,41(2):660-672. DOI：

CAO Jingya,YANG Shengxiong,TANG Danling,et al.Mg/Ca, Ba/Ca, and S/Ca ratios as environmental and growth proxies for bivalve shells from the Haima cold seep, South China Sea[J].Journal of Oceanology and Limnology,2023,41(02):660-672. DOI：

摘要

Abstract

Bivalve shell fossils

cemented by authigenic carbonates

are widely spread in the Haima cold seep

Qiongdongnan Basin of the South China Sea (SCS). In this study

we examined an element profile of

Gigantidas platifrons

in the Haima cold seeps at a water depth of 1 381 m. Based on the scanning electron microscope (SEM) analyses

the prismatic layer and nacreous layer were identified

which are characterized by prismatic structure and stratified structure

respectively. In addition

the profile can be subdivided into two parts: altered and unaltered zones. Laser inductively coupled plasma mass spectrometry (LA-ICP-MS) mapping shows that the element concentrations of the altered zones were influenced by the authigenic carbonate rocks

whereas the element concentrations of unaltered zones remain stable. In-situ X-ray diffraction (XRD) analyses show that the mineral constituent of the prismatic layer is mainly composed of aragonite. Along with the growth profile

Mg/Ca ratios of unaltered zones have minor variations

ranging 0.72–0.97 mmol/mol (mean=0.87 mmol/mol)

with

estimated temperatures of 3.8–4.1 °‍‍C

indicating that the temperature of the surrounding seawater remains constant and agree with the measured data of 3.9 °‍‍C which was conducted by a conductivity-temperature-depth system (CTD). The minor variations of Ba/Ca ratios (0.01–0.06 mmol/mol; mean=0.04 mmol/mol) indicate a relatively stabilized salinity of the surrounding seawater. S/Ca ratios show large variations of 0.04–4.15 mmol/mol (mean=1.37 mmol/mol). S/Ca ratios have regular variations which generally correspond to the variations of the Mg/Ca ratios

highlighting that the S/Ca ratios of bivalve shells show the potential to reflect the growth rate of the

Gigantides

. However

further studies should be carried out on the understanding of the links between the S/Ca ratios and seepage intensity of cold-seep fluids.

关键词

Keywords

references

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