Geochemical characteristics of cold-seep carbonates in Shenhu area, South China Sea

Chongmin CHEN; Lifeng ZHONG; Zhifeng WAN; Chiyu CHENG; Wei ZHOU; Xing XU

doi:10.1007/s00343-021-1112-z

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Geochemical characteristics of cold-seep carbonates in Shenhu area, South China Sea

Geology | Updated：2023-05-20

- Geochemical characteristics of cold-seep carbonates in Shenhu area, South China Sea
- Journal of Oceanology and Limnology Vol. 40, Issue 3, Pages: 969-985(2022)
- Affiliations：
  
  1.School of Marine Sciences, Guangdong Provincial Key Laboratory of Marine Resources and Coastal Engineering, Sun Yat-sen University, Zhuhai 519000, China
  2.Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai 519000, China
  3.MLR Key Laboratory of Marine Mineral Resources, Guangzhou Marine Geological Survey, Ministry of Natural Resources, Guangzhou 510075, China
- Author bio：
  
  Lifeng ZHONG, zhonglifeng@sml-zhuhai.cn
  Zhifeng WAN, wanzhif@mail.sysu.edu.cn
- Funds：
- DOI：10.1007/s00343-021-1112-z
  CLC：
- Published：2022-03
- Accepted：
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Chongmin CHEN, Lifeng ZHONG, Zhifeng WAN, et al. Geochemical characteristics of cold-seep carbonates in Shenhu area, South China Sea[J]. Journal of Oceanology and Limnology, 2022, 40(3): 969-985.
DOI：

Chongmin CHEN, Lifeng ZHONG, Zhifeng WAN, et al. Geochemical characteristics of cold-seep carbonates in Shenhu area, South China Sea[J]. Journal of Oceanology and Limnology, 2022, 40(3): 969-985. DOI： 10.1007/s00343-021-1112-z.

摘要

Abstract

Cold seeps spread worldwide along the continental margins

which are closely related to the exploration of gas hydrates. Cold-seep carbonates have been reported to record the nature of seepage

including fluid source

sedimentary environment

and variation of seepage activity. We investigated the morphology

mineralogy

element compositions

and carbon and oxygen isotopes of 15 cold-seep carbonates collected from the Shenhu area

and compared them with 2 carbonates from the Haima cold seep

the South China Sea (SCS)

to promote our knowledge of cold-seep system in SCS. Most of the Shenhu carbonates exhibit crust morphology

and some are in the form of chimneys and blocks. Their absolute (20%–65%) and relative carbonate mineral contents (mainly aragonite and calcite

with minor samples containing dolomite) vary significantly

indicating the multi-stage methane leakage in our study area. Some samples show a slight negative Ce anomaly

suggesting either the mixing of seawater or variation of the redox condition during the precipitation; the cooccurrence of strongly enriched U and Mo demonstrates anoxic condition during precipitation. The mixed genetic methane source was interpreted by δ

C of the Shenhu carbonates to range from -22.34‰ to -59.30‰ Vienna PeeDee Belemnite (VPDB)

and the slight

O-enrichment imprinted on the carbonates suggests the possible influence from hydrate dissociation. The Haima carbonates

with biogenic methane as the main gas source

were presumably formed in a stronger fluid flux by compared with our Shenhu samples.

关键词

Keywords

references

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